The single mass analyzer CIMS (S-CIMS) was developed for use on NASA’s ER-2 aircraft. Its first measurements were made in 2000 (SOLVE, see photo). Subsequently, it has flown on the NASA DC-8 aircraft for INTEX-NA, DICE, TC4, ARCTAS, ATom, KORUS, FIREX, as well as on the NCAR C-130 during MILAGRO/INTEX-B. HNO3 is measured by selective ion chemical ionization via the fluoride transfer reaction: CF3O- + HNO3 → HF • NO3- + CF2O In addition to its fast reaction rate with HNO3, CF3O- can be used to measure additional acids and nitrates as well as SO2 [Amelynck et al., 2000; Crounse et al., 2006; Huey et al., 1996]. We have further identified CF3O- chemistry as useful for the measurement of less acidic species via clustering reactions [Crounse et al., 2006; Paulot et al., 2009a; Paulot et al., 2009b; St. Clair et al., 2010]: CF3O- + HX → CF3O- • HX where, e.g., HX = HCN, H2O2, CH3OOH, CH3C(O)OOH (PAA) The mass analyzer of the S-CIMS instrument was first upgraded from a quadrupole to a unit-mass resolution time-of-flight (ToF) analyzer. In 2023, the mass filter was again upgraded to an 1m flight path (~5000 deltaM/M). The ToF admits the sample ion beam to the ion extractor, where a pulse of high voltage orthogonally deflects and accelerates the ions into the reflectron, which in turn redirects the ions toward the multichannel plate detector. Ions in the ToF follow a V-shaped from the extractor to detector, separating by mass as the smaller ions are accelerated to greater velocities by the high voltage pulse. The detector collects the ions as a function of time following each extractor pulse. The rapid-scan collection of the ToF guarantees a high temporal resolution (1 Hz or faster) and simultaneous data products from the S-CIMS instrument for all mass channels [Drewnick et al., 2005]. We have flown a tandem CIMS (TCIMS) instrument in addition to the SCIMS since INTEX-B (2006). The T-CIMS provides parent-daughter mass analysis, enabling measurement of compounds precluded from quantification by the S-CIMS due to mass interferences (e.g. MHP) or the presence of isobaric compounds (e.g. isoprene oxidation products) [Paulot et al., 2009b; St. Clair et al., 2010]. Calibrations of both CIMS instruments are performed in flight using isotopically-labeled reagents evolved from a gas cylinders or from a thermally-stabilized permeation tube oven [Washenfelder et al., 2003]. By using an isotopically labeled standard, the product ion signals are distinct from the natural analyte and calibration can be performed at any time without adversely affecting the ambient measurement.
DC-8 - AFRC
Developed by Droplet Measurement Technologies, the CFSTGC is based on a concept by Roberts and Nenes [2005]. The instrument counts the fraction of aerosol particles that become droplets when exposed to a given water vapor supersaturation (RH > 100%).
As with all CCN counters, a temperature gradient is applied to produce a supersaturation of water vapor. However, the mechanism for generating supersaturation is not the same for all CCN counters. For example, for continuous flow parallel plate diffusion chambers, the temperature gradient is perpendicular to the flow, and supersaturation is a result of the nonlinear dependence of vapor pressure upon temperature. The same mechanism applies for static diffusion cloud chambers, where there is no flow at all.
However, as the name implies, for the Continuous Flow Streamwise Thermal Gradient CCN Counter, the temperature gradient is in the streamwise direction (maintained by thermoelectric coolers). In this case, supersaturation results as a consequence of the greater rate of mass transfer over heat transfer.
With laminar flow, heat and water vapor are transferred to the centerline of the column from the walls only by diffusion.
Since molecular diffusivity is greater than thermal diffusivity, the distance downstream that a water molecule travels before reaching the centerline is less than the distance the heat travels downstream before reaching the centerline. If you pick a point at the centerline, the heat originated from a greater distance upstream than the water vapor.
There are four facts that are necessary to explain how supersaturation is generated within the CFSTGC:
1) Assuming that the inner surface of the column is saturated with water vapor at all points, since the temperature is greater at point B than at point A, the water vapor partial pressure is also greater at point B than at point A.
2) The actual partial pressure of water vapor at point C is equal to the partial pressure of water vapor at point B.
3) However, since the temperature at point C is the same as at point A, the equilibrium water vapor pressure at point C is equal to the water vapor partial pressure at point A.
4) The saturation ratio is the ratio between the actual partial pressure of water vapor and the equilibrium vapor pressure. This is equivalent to the partial pressure at point B divided by the partial pressure at point A, which is always greater than one. Thus supersaturation is generated through a dynamic equilibrium.
This multipurpose particle spectrometer includes three Droplet Measurement Technologies instruments plus temperature and relative humidity sensors that are packaged into a single, integrated measurement system. The CAPS provides the following data:
- Aerosol particle and cloud hydrometeor size distributions from 0.51 to 50 µm
- Precipitation size distributions from 25 µm to 1550 µm, or 15-930 um with optional 15-micron resolution
- Particle optical properties (refractive index)
- Particle shape assessments (discrimination between water and ice for probes with depolarization feature)
- Liquid water content from 0.01 to 3 g/m3
- Aircraft velocity
- Atmospheric temperature and pressure
This instrument replaces the older PMS/PMI FSSP-100, FSSP-300, 2D-C, 2D-P and KLWC and can be used in many applications, including weather modification, aircraft icing, hurricane and storm research, and agricultural and industrial spray characterization.
The Charged-coupled device Actinic Flux Spectroradiometers (CAFS) instruments measure in situ down- and up-welling radiation and combine to provide 4 pi steradian actinic flux density spectra from 280 to 650 nm. The sampling resolution is ~0.8 nm with a full width at half maximum (FWHM) of 1.7 nm at 297 nm. From the measured flux, photolysis frequencies are calculated for ~40 important atmospheric trace gases including O3, NO2, HCHO, HONO and NO3 using a modified version of the NCAR Tropospheric Ultraviolet and Visible (TUV) radiative transfer model. The absolute spectral sensitivity of the instruments is determined in the laboratory with 1000 W NIST-traceable tungsten-halogen lamps with a wavelength dependent uncertainty of 3–5%. During deployments, spectral sensitivity is assessed with secondary calibration lamps while wavelength assignment is tracked with Hg line sources and comparisons to spectral features in the extraterrestrial flux. The optical collectors are characterized for angular and azimuthal response and the effective planar receptor distance. CAFS have an excellent legacy of performance on the NASA DC-8 and WB-57 platforms during atmospheric chemistry and satellite validation mission. These include AVE Houston 2004 and 2005, PAVE, CR-AVE, TC4, ARCTAS, DC3, SEAC4RS, KORUS-AQ, ATom and FIREX-AQ. For FIREX-AQ, upgraded electronics and cooling reduced noise and allowed for a decrease to 1 Hz acquisition.
The Broadband CO2 lidar instrument operates on the principle of differential absorption. This means that the instrument examines the transmission of light through the atmosphere at two or more different wavelengths that are absorbed differently by the species one wishes to measure. There are then two principal elements involved in the measurement—the source and the detector. Passive systems use natural processes such as sunlight or atmospheric emission to generate a number of different wavelengths which are separated for analysis by the detector. Most laser based systems (eg. DIAL lidars) use two or more different laser sources to provide different wavelengths. These systems then might use the same detector for the multiple wavelengths using time separation or modulation to differentiate the signals coming from the different lasers.
This system, however, uses as a detector that can differentiate wavelengths just as conventional passive sensors. The detector was originally developed as the Fabry-Perot passive sensor measuring CO2 using reflected sunlight. Our new approach is made possible by the emergence of a new type of source—the superluminescent light emitting diode (SLED). The SLED has the same high brightness and collimation characteristics as a conventional laser but it emits light over a broader range of wavelengths than conventional lasers. This permits a differential absorption measurement employing a single source with wavelength differentiation in the detector.
The Broadband Radiometers (BBR) consist of modified Kipp & Zonen CM-22 pyranometers (to measure solar irradiance) and CG-4 pyrgeometers (to measure IR irradiance) (see http://www.kippzonen.com/). The modifications to make these instruments more suitable for aircraft use include new instrument housings and amplification of the signal at the sensor. The instruments are run in current-loop mode to minimize the effects of noise in long signal cables. The housing is sealed and evacuated to prevent condensation or freezing inside the instrument. Each BBR has the following properties: Field-of-view: Hemispheric Temperature Range: -65C to +80C Estimated Accuracy: 3-5% Data Rate: 1Hz
The Airborne Topographic Mapper (ATM) was a scanning LIDAR developed and used by NASA for observing the Earth's topography for several scientific applications, foremost of which is the measurement of changing arctic and antarctic icecaps and glaciers. It typically flies on aircraft at an altitude between 400 and 800 meters above ground level, and measures topography to an accuracy of ten to twenty centimeters by incorporating measurements from GPS (global positioning system) receivers and inertial navigation system (INS) attitude sensors.
The ATM instruments was based at NASA's Wallops Flight Facility (WFF) in Virginia. They commonly fly aboard the NASA P3-B based at WFF and have flown aboard other P-3 aircraft, the NASA DC-8, several twin-otters (DHC-6), and a C-130; they can fly on most Twin Otter/King Air-class aircraft. The ATM has flown surveys in Greenland nearly every year since 1993. Other uses have included measurement of sea ice, verification of satellite radar and laser altimeters, and measurement of sea-surface elevation and ocean wave characteristics. The altimeter often flies in conjunction with a variety of other instruments. The ATM has been participating in NASA's Operation IceBridge since 2009.
The ATM program was terminated in 2022.
ATHOS uses laser-induced fluorescence (LIF) to measure OH and HO2 simultaneously. OH is both excited and detected with the A2Σ+ (v’=0) → X2π (v”=0) transition near 308 nm. HO2 is reacted with reagent NO to form OH and is then detected with LIF. The laser is tuned on and off the OH wavelength to determine the fluorescence and background signals. ATHOS can detect OH and HO2 in clear air and light clouds from Earth's surface to the lower stratosphere. The ambient air is slowed from the aircraft speed of 240 m/s to 8-40 m/s in an aerodynamic nacelle. It is then pulled by a vacuum pump through a small inlet, up a sampling tube, and into two low-pressure detection cells - the first for OH and the second for HO2. Detection occurs in each cell at the intersection of the airflow, the laser beam, and the detector field-of-view.
This is a stratospheric lidar which is configured to fly on the NASA DC-8. It is a zenith viewing instrument, which makes vertical profile measurements of ozone, aerosols and temperature. Stratospheric ozone can be measured at solar zenith angles greater than ~30 degrees, while temperature and aerosols require SZA > 90 degrees. The SNR is maximized under dark coonditions. The measurement of Near-field water vapor measurements is being investigated and could be readily implemented. The instrument utilizes a XeCl excimer laser and a Nd-YAG laser to make DIAL, Raman DIAL, and backscatter measurements. A zenith viewing 16" telescope receives the lidar returns.