CU Aircraft High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-AMS)

Status

Operated By: 
PI

HR-AMS instrument installed on the NASA DC-8 for ATom-1

Principle: The CU aircraft version of the Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) detects non-refractory submicron aerosol composition by impaction on a vaporizer at 600°C, followed by electron ionization and time-of-flight mass spectral analysis. Size-resolved composition can be quantified by measuring the arrival times of the aerosol at the vaporizer.

Aircraft Operation: (1 min cycles, can be adjusted to meet mission goals):
46 s total concentration measurements (1 s resolution, can be increased to up to 10 Hz upon request)
5 s speciated size distribution measurements (with improved S/N detection due to ePToF acquisition)
9 s Background + Overhead
Higher accuracy due to flight day calibrations using built-in system
Custom pressure controlled inlet with confirmed performance up to 41 kft

Real Time Data Products: 
PM1 Aerosol Mass Concentrations:
Organic aerosol (OA) , SO4, NO3, NH4, Chloride 
OA Chemical Markers: f44 (Secondary OA), f57 (hydrocarbon-like OA), f60 (biomass burning OA), f82 (isoprene epoxide-SOA), other fx upon request

More Advanced Products:
- PM1 Seasalt, ClO4, total I, total Br, MSA concentrations
- O/C, H/C, OA/OC, OSc
- Particle organic nitrates (pRONO2)
- Ammonium Balance, estimated pH
- OA components by positive matrix factorization (PMF)
- Particle eddy covariance fluxes of all species

Detection Limits (1s, ng sm-3), (1 min, ng sm-3) from start of the flight (due to custom cyropump):
Sulfate: 40, 15
Nitrate: 15, 6
Ammonium: 3, 1
Chloride: 30, 12
OA: 200, 80
For detailed OA analysis, longer averaging (3-30 s, depending on OA concentration) is needed. A 1 min product is hence provided as well.

 

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