NASA - National Aeronautics and Space Administration

The Submillimeterwave Limb Sounder (SLS) is a heterodyne radiometer measuring thermal emission spectra near 640 GHz (for detection of ClO, HCl, and O3) and 604 GHz. (for detection of HNO3 and N2O) designed for use on high altitude balloons and aircraft. The instrument consists of five subsystems:

-optics which define the instrument field of view (FOV)
-radiometer front-ends which down converts incoming radiance signals
-intermediate frequency (IF) stage which selects and frequency shifts signal bands
-spectrometers which frequency resolve and detect the incoming power spectrum
-command and data handling which controls the instrument and transmits data to the ground

Limb scanning is accomplished by a flat mirror (~20 cm diameter) connected to a stepper motor (0.2 steps) and 14 bit position encoder. This mirror is also used for gain and zero calibration by viewing an absorber target located below the mirror and upward at 47° elevation angle to view the cold sky. A set of three off-axis parabolic reflectors form the instrument field of view (0.35 full width at half maximum) and couple limb radiance to the mixer input waveguide. These reflectors are oversized (~30 dB edge taper) to minimize side lobes in the FOV. Pointing and beam shape were verified by scanning the instrument FOV across the emission from a 600 GHz transmitter (multiplied output of a Gunn oscillator) located in the receiver optical far-field.

The radiometer front-end is an uncooled second harmonic mixer using a waveguide mounted Schottky diode. The radiometer is operated double side band (DSB), i.e., spectral features occurring symmetrically above and below the effective local oscillator frequency (637.050 GHz) appear together in the IF output spectrum. The diode is pumped at a 318.525 GHz. This source is generated by a tripled 106.175 GHz phase-locked InP Gunn oscillator and wave guide coupled to the mixer block. The mixer produces an IF output spectrum of 10.5 to 13 GHz, which corresponds to signals at the mixer input at 647.5 GHz to 650.0 GHz (in the radiometer upper side band) and 626.5 GHz to 624.1 GHz ( in the lower side band). The design of the 604 GHz radiometer system is similar to 637 GHz system but operates at a lower IF frequency of 2 to 3 GHz.

Diagram of the SLS frequency down-conversion scheme. RF signals enter the signal flow path through mixer feeds at the left of the diagram. At the right side, the signal flow enters a set of UARS MLS-type filterbank spectrometers where bands are further spectrally resolved, power detected, and digitized.

PANTHER uses Gas Chromatography with Electron Capture Detection and (GC-ECD) and Gas Chromatography with Mass Selective Detection (GC-MSD) to measure numerous trace gases, including methyl halides, HCFCs, peroxyacetyl nitrate, nitrous oxide, SF6, CFC-12, CFC-11, Halon-1211, methyl chloroform, carbon tetrachloride.

3 ECDs with packed columns (OV-101, Porapak-Q, molecular sieve).

1 ECD with a TE (thermal electric) cooled RTX-200 capillary column.

2-channel MSD (mass selective detector). The MSD analyzes two independent samples air concentrated onto TE cooled Haysep traps, which are then heated to desorb the analytes and separate using through two temperature programmed RTX-624 capillary columns.

With the exception of PAN, all channels of chromatography are normalized to a stable in-flight calibration gas references to NOAA scales. The PAN data are normalized to an in-flight PAN source of ≈ 100 ppt with ±5 % reproducibility. This source is generated by efficient photolytic conversion of NO in the presence of acetone. Detector non-linearity is taken out by lab calibrations for all molecules.

The MkIV interferometer operates in solar absorption mode, meaning that direct sunlight is spectrally analyzed and the amount of various gases at different heights in the Earth's atmosphere is derived from the shapes and depths of their absorption lines. The optical design of the MkIV interferometer is based largely on that of the ATMOS instrument, which has flown four times on the Space Shuttle. The first three mirrors in the optical path comprise the suntracker. Two of these mirrors are servo-controlled in order to compensate for any angular motion of the observation platform. The subsequent wedged KBr plates, flats, and cube-corner retro-reflectors comprise a double-passed Michelson interferometer, whose function is to impart a wavelength-dependent modulation to the solar beam. This is achieved by sliding one of the retro-reflectors at a uniform velocity so that the recombining beams interfere with each other. A paraboloid then focusses the solar beam onto infrared detectors, which measure the interferometrically modulated solar signal. Finally, Fourier transformation of the recorded detector outputs yields the solar spectrum. An important advantage of the MkIV Interferometer is that by employing a dichroic to feed two detectors in parallel, a HgCdTe photoconductor for the low frequencies (650-1850 cm-1) and a InSb photodiode for the high frequencies (1850-5650 cm-1), the entire mid-infrared region can be observed simultaneously with good linearity and signal-to-noise ratio. In this region over 30 different gases have identifiable spectral signatures including H2O, O3, N2O, CO, CH4, NO, NO2, HNO3, HNO4, N2O5, H2O2, ClNO3, HOCl, HCl, HF, COF2, CF4, SF6, CF2ClCFCl2, CHF2Cl, CF2Cl2, CFCl3, CCl4, CH3Cl, C2H2, C2H6, OCS, HCN, N2, O2, CO2 and many isotopic variants. The last three named gases, having well known atmospheric abundances, are important in establishing the observation geometry of each spectrum, which otherwise can be a major source of uncertainty. Similarly, from analysis of T-sensitive CO2 lines, the temperature profile can be accurately determined. The simultaneity of the observations of all these gases greatly simplifies the interpretation of the results, which are used for testing computer models of atmospheric transport and chemistry, validation of satellite data, and trend determination.

Although the MkIV can measure gas column abundances at any time during the day, the highest sensitivity to atmospheric trace gases is obtained by observing sunrise or sunset from a balloon. The very long (~ 400 km) atmospheric paths traversed by incoming rays in this observation geometry also make this so-called solar occultation technique insensitive to local contamination.

The in‐situ diode laser spectrometer system, referred to by its historical name DACOM, includes three tunable diode lasers providing 4.7, 4.5, and 3.3 μm radiation for accessing CO, N2O, and CH4 absorption lines, respectively. The three laser beams are combined by the use of dichroic filters and are then directed through a small volume (0.3 liter) Herriott cell enclosing a 36 meter optical path. As the three coincident laser beams exit the absorption cell, they are spectrally isolated using dichroic filters and are then directed to individual detectors, one for each laser wavelength. Wavelength reference cells containing CO, CH4, and N2O are used to wavelength lock the operation of the three lasers to the appropriate absorption lines. Ambient air is continuously drawn through a Rosemount inlet probe and a permeable membrane dryer which removes water vapor before entering the Herriott cell and subsequently being exhausted via a vacuum pump to the aircraft cabin. To minimize potential spectral overlap from other atmospheric species, the Herriott cell is maintained at a reduced pressure of ~90 Torr. At 5 SLPM mass flow rate, the absorption cell volume is exchanged nominally twice per second. Frequent but short calibrations with well documented and stable reference gases are critical to achieving both high precision and accuracy. Calibration for all species is accomplished by periodically (~4 minutes) flowing calibration gas through this instrument. Measurement accuracy is closely tied to the accuracy of the reference gases obtained from NOAA/ESRL, Boulder, CO. Both CO and CH4 mixing ratios are provided in real-time to investigators aboard the DC‐8.

Argus is a two channel, tunable diode laser instrument set up for the simultaneous, in situ measurement of CO (carbon monoxide), N2O (nitrous oxide) and CH4 (methane) in the troposphere and lower stratosphere. The instrument measures 40 x 30 x 30 cm and weighs 21 kg. An auxiliary, in-flight calibration system has dimensions 42 x 26 x 34 cm and weighs 17 kg.

The instrument is an absorption spectrometer operating in rapid scan, secondharmonic mode using frequency-modulated tunable lead-salt diode lasers emitting in the mid-infrared. Spectra are co-added for two seconds and are stored on a solid state disk for later analysis. The diode laser infrared beam is shaped by two anti-refection coated lenses into an f/40 beam focused at the entrance aperture of a multi-pass Herriott cell. The Herriott cell is common to both optical channels and is a modified astigmatic cell (New Focus Inc., Santa Clara, California).

The aspherical mirrors are coated with protected silver for optimal infrared reflectivity. The cell is set up for a 182-pass state for a total path of 36m. The pass number can be confirmed by visual spot pattern verification on the mirrors observed through the glass cell body when the cell is illuminated with a visible laser beam. However, instrument calibration is always carried out using calibrated gas standards with the Argus instrument operating at its infrared design wavelengths, 3.3 and 4.7 micrometers respectively for CH4 and CO detection. The electronic processing of the second harmonic spectra is done by standard phase sensitive amplifier techniques with demodulation occurring at twice the laser modulation frequency of 40 kHz. To optimize the secondharmonic signal amplitude in a changing ambient pressure environment the laser modulation amplitude is updated every 2 seconds to its optimal theoretical value based upon the measured pressure in the Herriott cell.

ATLAS uses a tunable laser to detect an infrared-active target gas such as N2O, methane, carbon monoxide, or ozone. The laser source is tuned to an individual roto-vibrational line in an infrared absorption band of the target gas, and is frequency modulated at 2 kHz. The instrument detects the infrared target gas by measuring the fractional absorption of the infrared beam from the tunable diode laser as it traverses a multipass White cell containing an atmospheric sample at ambient pressure.

Synchronous detection of the resultant amplitude modulation at 2kHz and 4kHz yields the first and second harmonics of the generally weak absorption feature with high sensitivity (DI/I < 1E-5). Part of the main beam is split off through a short cell containing a known amount of the target gas to a reference detector. The reference first harmonic signal is used to lock the laser frequency to the absorption line center, while the second harmonic signal is used to derive the calibration factor needed to convert the measurement beam second harmonic amplitude into absolute gas concentration. A zero beam is included to correct for background gas absorption occurring outside the multipass cell. The response time of the instrument is set by the gas flow rate through the White cell, which is normally adjusted to give a new sample every second. Periodic standard additions of the target gas are injected into the sample stream as a second method to calibrate the measurement technique and as an overall instrument diagnostic.

ACATS-IV is a 4-channel gas chromatograph with electron capture detection (ECD) that measures a variety of halocarbons and other long-lived trace gases in the stratosphere. The instrument is currently configured to measure CFC-11 (CCl3F), CFC-12 (CCl2F2), CFC-113 (CCl2FCClF2), methyl chloroform (CH3CCl3), carbon tetrachloride (CCl4), halon-1211 (CBrClF2), chloroform (CHCl3), methane (CH4), and hydrogen (H2) every 125 s, and nitrous oxide (N2O) and sulfur hexafluoride (SF6) every 250 s. Each channel is comprised of a sample loop (2-10 cm3 volume), gas sampling valve (GSV), chromatographic column pair, ECD, electrometer, and several flow, temperature, and pressure controllers. In-flight calibration is carried out every 625 s (1250 s for N2O and SF6) by injecting a dried, whole air standard containing approximately 80% of tropospheric mixing ratios.

The Airborne Scanning Microwave Limb Sounder (A-SMLS) makes wide-swath vertical profile observations of the composition
of the upper troposphere and lower stratosphere (the atmospheric region from ~10–20km altitude). A-SMLS measurements are
well suited to studies of convective outflow, long-range pollution transport, and exchange of air between the
troposphere and stratosphere. These atmospheric processes have strong impacts on climate and air quality but are
currently incompletely understood. Improved understanding of these issues is one of the main goals of NASA’s atmospheric
composition Earth science focus area. A-SMLS airborne observations reflect the priority spaceborne “Ozone and Trace Gas”
observables identified in the recent Decadal Survey.

A-SMLS was initially developed and flown on the WB-57 under the NASA Instrument Incubator Program (IIP), following
which, it was adapted to the ER-2 platform. Subsequent work, funded under an additional IIP, has upgraded the receivers
to ones that require cooling to only 70K rather than the previously needed 4K, and to use newer technology digital
spectrometers. Test flights for A-SMLS in this new configuration are planned, but further work, proposed here, is needed
to make the instrument fully “campaign ready”.

A-SMLS observes a ~300km-wide swath ~300km ahead of the aircraft in a 2D raster scan (azimuth and elevation), with
~10x10km horizontal sampling (across and along-track). As typically configured, A-SMLS measures water vapor, ozone, and
carbon monoxide. Retuning of the instrument (including in flight) can provide measurements of other species (including
N2O, HCN, CH3CN, H2CO, and others).

The instrument would be a particularly valuable addition to multi-aircraft campaigns. The broad swath A-SMLS
observations from the ER-2 could be used in near-real-time to help guide lower altitude aircraft carrying in situ
sensors to regions of interest.

As part of NASA's Airborne Instrument Technology Transition (AITT) program, the instrument is currently being updated to
help cement its suitability for campaign-mode operations, specifically, this involves:

- Addition of a liquid cooling loop to transfer waste heat from the existing ~70K cryocooler to the outer skin of the
ER-2 wing pod.

- Development of an “intelligent scan” system that accounts for aircraft orientation etc. when performing the 2D
raster limb scan on the atmosphere.

- Completion of a thorough ground-based instrument calibration.

- Development of an on-board radiance compression scheme that will enable key data to be transferred to the ground for
use in real-time flight planning as described above.

- Updates to the analysis algorithms software used for Aura MLS, enabling their application to A-SMLS observations.

ALIAS (Aircraft Laser Infrared Absorption Spectrometer) measures total water, total water isotopes, carbon monoxide, and carbon dioxide isotope ratios. No other instrument provides real-time measurements of carbon dioxide isotope ratios which are clear identifiers of atmospheric transport (18O/17O/16O for stratospheric intrusion, 13C/12C for anthropogenic signals). ALIAS easily adapts to changing mission priorities and can be configured to measure HCl, CH4, SO2, and N2O by simply replacing a semiconductor laser. These measurements contribute to Atmospheric Composition Focus Area research by providing key data on how convective processes affect stratospheric composition, the development of cirrus particles and their affect on Earth's radiative balance, and health of the ozone layer through measurement of chlorine partitioning.

The Airborne Laser Infrared Absorption Spectrometer (ALIAS-II) is a very high resolution scanning tunable diode laser spectrometer which makes direct, simultaneous measurements of selectable combinations of HCl, NO2, CO, CO2, CH4, and N2O at sub-part-per-billion levels over a 3-30 second integration time. The measurement technique is based upon using tunable lead-salt and/or quantum cascade lasers operating from 3.4 to 8 microns wavelength scanning over absorption lines at 10 Hz recording second harmonic spectra. The instrument features an open-cradle multipass Herriott absorption cell with 15.24-cm diameter spherical zerodur mirrors coated with gold on chrome. The separation between the mirrors is adjustable allowing for a relatively small cell (0.75-m to 1.5-m) to contain an optical path length up to 120-m, depending on the spacing of the mirrors. Lasers and detectors are contained in a lightweight aluminum liquid nitrogen Dewar which can achieve a 28-hour hold time with only a 2 liter charge of liquid nitrogen. The instrument features custom laser current drives, signal chains, InSb detectors and preamps, 16-bit signal averager, analog signal conditioner, and digital I/O which are controlled by an onboard Pentium processor. Data is written to a ruggedized 2-Gb hard disk every 30 seconds and simultaneously transmitted via telemetry to ground station computers which provide backup storage of the data. The instrument weighs 36 kg and requires <56 watts for operation. Additional power up to 250 watts is available for structural heaters and current draw varies with atmospheric conditions.