NASA - National Aeronautics and Space Administration

The SAFS instruments determine wavelength dependent actinic flux from 280-420 nm. The actinic flux in combination with the absorption cross section and quantum yield molecular data will be used to calculate the photolysis frequencies of multiple photochemically important molecular processes, including O3, NO2, HONO, CH2O, H2O2, CH3OOH, HNO3, PAN, CH3NO3, CH3CH2NO3, and CH3COCH3.

The SAFS measurement is based on a 2p steradian hemisphere hemispherical quartz light collector, a double monochromator, and a low dark current photomultiplier. The monochromator employs dual 2400 G/mm gratings which produce a 1 nm FWHM spectral resolution and very low straylight. The instrument package on the aircraft includes two independent, but time synchronized (IRIG-B) spectroradiometer systems to measure the up- and down-welling fluxes in a 10 second scan time. Summing these produces the spherically integrated actinic flux.

The NOAA-O3 instrument consists of a mercury lamp, two sample chambers that can be periodically scrubbed of ozone, and two detectors that measure the 254-nm radiation transmitted through the chamber. The ozone absorption cross-section at this wavelength is accurately known; hence, the ozone number density can be easily calculated. Since the two absorption chambers are identical, virtually continuous measurements of ozone are made by alternating the ambient air sample and ozone scrubbed sample between the two chambers. At a one-second data collection rate, the minimum detectable concentration of ozone (one standard deviation) is 1.5 x 10 10 molecules/cm 3 (0.6ppbv at STP).

The Microwave Temperature Profiler (MTP) is a passive microwave radiometer, which measures the natural thermal emission from oxygen molecules in the earth’s atmosphere for a selection of elevation angles between zenith and nadir. The current observing frequencies are 55.51, 56.65 and 58.80 GHz. The measured "brightness temperatures" versus elevation angle are converted to air temperature versus altitude using a quasi-Bayesian statistical retrieval procedure. The MTP has no ITAR restrictions, has export compliance classification number EAR99/NLR. An MTP generally consists of two assemblies: a sensor unit (SU), which receives and detects the signal, and a data unit (DU), which controls the SU and records the data. In addition, on some platforms there may be a third element, a real-time analysis computer (RAC), which analyzes the data to produce temperature profiles and other data products in real time. The SU is connected to the DU with power, control, and data cables. In addition the DU has interfaces to the aircraft navigation data bus and the RAC, if one is present. Navigation data is needed so that information such as altitude, pitch and roll are available. Aircraft altitude is needed to perform retrievals (which are altitude dependent), while pitch and roll are needed for controlling the position of a stepper motor which must drive a scanning mirror to predetermined elevation angles. Generally, the feed horn is nearly normal to the flight direction and the scanning mirror is oriented at 45-degrees with respect to receiving feed horn to allow viewing from near nadir to near zenith. At each viewing position a local oscillator (LO) is sequenced through two or more frequencies. Since a double sideband receiver is used, the LO is generally located near the "valley" between two spectral lines, so that the upper and lower sidebands are located near the spectral line peaks to ensure the maximum absorption. This is especially important at high altitudes where "transparency" corrections become important if the lines are too "thin." Because each frequency has a different effective viewing distance, the MTP is able to "see" to different distances by changing frequency. In addition, because the viewing direction is also varied and because the atmospheric opacity is temperature and pressure dependent, different effective viewing distances are also achieved through scanning in elevation . If the scanning is done so that the applicable altitudes (that is, the effective viewing distance times the sine of the elevation angle) at different frequencies and elevation angles are the same, then inter-frequency calibration can also be done, which improves the quality of the retrieved profiles. For a two-frequency radiometer with 10 elevation angles, each 15-second observing cycle produces a set of 20 brightness temperatures, which are converted by a linear retrieval algorithm to a profile of air temperature versus altitude, T(z). Finally, radiometric calibration is performed using the outside air temperature (OAT) and a heated reference target to determine the instrument gain. However, complete calibration of the system to include "window corrections" and other effects, requires tedious analysis and comparison with radiosondes near the aircraft flight path. This is probably the most important single factor contributing to reliable calibration. For stable MTPs, like that on the DC8, such calibrations appear to be reliable for many years. Such analysis is always performed before MTP data are placed on mission archive computers.

The nucleation-mode aerosol size spectrometer (NMASS) measures the concentration of particles as a function of diameter from approximately 4 to 60 nm. A sample flow is continuously extracted from the free stream using a decelerating inlet and is transported to the NMASS. Within the instrument, the sample flow is carried to 5 parallel condensation nucleus counters (CNCs) as shown in Fig. 1. Each CNC is tuned to measure the cumulative concentration of particles larger than certain diameter. The minimum detectable diameters for the 5 CNCs are 4.0, 7.5, 15, 30 and 55 nm, respectively. An inversion algorithm is applied to recover a continuous size distribution in the 4 to 60 nm diameter range.

The NMASS has been proven particularly useful in measurements of nucleation-mode size distribution in environments where concentrations are relatively high and fast instrumental response is required. The instrument has made valuable measurements vicinity of cirrus clouds in the upper troposphere and lower stratosphere (WAM), in the near-field exhaust of flying aircraft (SULFUR 6), in newly created rocket plumes (ACCENT), and in the plumes of coal-fired power plants (SOS ’99). The instrument has flown on 3 different aircraft and operated effectively at altitudes from 50 m to 19 km and ambient temperatures from 35 to -80ºC.

Accuracy. The instrument is calibrated using condensationally generated particles that are singly charged and classified by differential electrical mobility. Absolute counting efficiencies are determined by comparison with an electrometer. Monte carlo simulations of the propagation of uncertainties through the numerical inversion algorithm and comparison with established laboratory techniques are used to establish accuracies for particular size distributions, and may vary for different particle size distributions. A study of uncertainties in aircraft plume measurements demonstrated a combined uncertainty (accuracy and precision) of 38%, 36% and 38% for number, surface and volume, respectively.

Precision. The precision is controlled by particle counting statistics for each channel. If better precision is desired, it is necessary only to accumulate over longer time intervals.

Response Time: Data are recorded with 10 Hz resolution, and the instrument has demonstrated response times of this speed in airborne sampling. However the effective response time depends upon the precision required to detect the change in question. Small changes may require longer times to detect. Plume measurements with high concentrations of nucleation-mode particles may be processed at 10 Hz.

Specifications: Weight is approximately 96 lbs, including an external pump. External dimensions are approximately 15”x16”x32”. Power consumption is 350 W at 28 VDC, including the pump.

The MkIV interferometer operates in solar absorption mode, meaning that direct sunlight is spectrally analyzed and the amount of various gases at different heights in the Earth's atmosphere is derived from the shapes and depths of their absorption lines. The optical design of the MkIV interferometer is based largely on that of the ATMOS instrument, which has flown four times on the Space Shuttle. The first three mirrors in the optical path comprise the suntracker. Two of these mirrors are servo-controlled in order to compensate for any angular motion of the observation platform. The subsequent wedged KBr plates, flats, and cube-corner retro-reflectors comprise a double-passed Michelson interferometer, whose function is to impart a wavelength-dependent modulation to the solar beam. This is achieved by sliding one of the retro-reflectors at a uniform velocity so that the recombining beams interfere with each other. A paraboloid then focusses the solar beam onto infrared detectors, which measure the interferometrically modulated solar signal. Finally, Fourier transformation of the recorded detector outputs yields the solar spectrum. An important advantage of the MkIV Interferometer is that by employing a dichroic to feed two detectors in parallel, a HgCdTe photoconductor for the low frequencies (650-1850 cm-1) and a InSb photodiode for the high frequencies (1850-5650 cm-1), the entire mid-infrared region can be observed simultaneously with good linearity and signal-to-noise ratio. In this region over 30 different gases have identifiable spectral signatures including H2O, O3, N2O, CO, CH4, NO, NO2, HNO3, HNO4, N2O5, H2O2, ClNO3, HOCl, HCl, HF, COF2, CF4, SF6, CF2ClCFCl2, CHF2Cl, CF2Cl2, CFCl3, CCl4, CH3Cl, C2H2, C2H6, OCS, HCN, N2, O2, CO2 and many isotopic variants. The last three named gases, having well known atmospheric abundances, are important in establishing the observation geometry of each spectrum, which otherwise can be a major source of uncertainty. Similarly, from analysis of T-sensitive CO2 lines, the temperature profile can be accurately determined. The simultaneity of the observations of all these gases greatly simplifies the interpretation of the results, which are used for testing computer models of atmospheric transport and chemistry, validation of satellite data, and trend determination.

Although the MkIV can measure gas column abundances at any time during the day, the highest sensitivity to atmospheric trace gases is obtained by observing sunrise or sunset from a balloon. The very long (~ 400 km) atmospheric paths traversed by incoming rays in this observation geometry also make this so-called solar occultation technique insensitive to local contamination.

The JPL Laser Hygrometer (JLH) is an autonomous spectrometer to measure atmospheric water vapor from airborne platforms. It is designed for high-altitude scientific flights of the NASA ER-2 aircraft to monitor upper tropospheric (UT) and lower stratospheric (LS) water vapor for climate studies, atmospheric chemistry, and satellite validation. JLH will participate in the NASA SEAC4RS field mission this year. The light source for JLH is a near-infrared distributed feedback (DFB) tunable diode laser that scans across a strong water vapor vibrational-rotational combination band absorption line in the 1.37 micrometer band. Both laser and detector are temperature‐stabilized on a thermoelectrically-cooled aluminum mount inside an evacuated metal housing. A long optical path is folded within a Herriott Cell for sensitivity to water vapor in the UT and LS. A Herriott cell is an off-axis multipass cell using two spherical mirrors [Altmann et al., 1981; Herriott et al., 1964]. The laser beam enters the Herriott cell through a hole in the mirror that is closest to the laser. The laser beam traverses many passes of the Herriott cell and then returns through the same mirror hole to impinge on a detector.

The high-sensitivity fast response CO2 instrument measures CO2 concentrations in situ using the light source, gas cells, and solid-state detector from a modified nondispersive infrared CO2 analyzer (Li-Cor, Inc., Lincoln, NE). These components are stabilized along the detection axis, vibrationally isolated, and housed in a temperature-controlled pressure vessel. Sample air enters a rear-facing inlet, is preconditioned using a Nafion drier (to remove water vapor), then is compressed by a Teflon diaphragm pump. A second water trap, using dry ice, reduces the sample air dewpoint to less than 70C prior to detection. The CO2 mixing ratio of air flowing through the sample gas cell is determined by measuring absorption at 4.26 microns relative to a reference gas of known concentration. In-flight calibrations are performed by replacing the air sample with reference gas every 10 minutes, with a low-span and a high-span gas every 20 minutes, and with a long-term primary standard every 2 hours. The long-term standard is used sparingly and serves as a check of the flight-to-flight accuracy and precision of the measurements, augmented by ground-based calibrations before and after flights.

The Meteorological Measurement System (MMS) is a state-of-the-art instrument for measuring accurate, high resolution in situ airborne state parameters (pressure, temperature, turbulence index, and the 3-dimensional wind vector). These key measurements enable our understanding of atmospheric dynamics, chemistry and microphysical processes. The MMS is used to investigate atmospheric mesoscale (gravity and mountain lee waves) and microscale (turbulence) phenomena. An accurate characterization of the turbulence phenomenon is important for the understanding of dynamic processes in the atmosphere, such as the behavior of buoyant plumes within cirrus clouds, diffusions of chemical species within wake vortices generated by jet aircraft, and microphysical processes in breaking gravity waves. Accurate temperature and pressure data are needed to evaluate chemical reaction rates as well as to determine accurate mixing ratios. Accurate wind field data establish a detailed relationship with the various constituents and the measured wind also verifies numerical models used to evaluate air mass origin. Since the MMS provides quality information on atmospheric state variables, MMS data have been extensively used by many investigators to process and interpret the in situ experiments aboard the same aircraft.

The Multiple-Angle Aerosol Spectrometer Probe (MASP) determines the size and concentration of particles from about 0.3 to 20 microns in diameter and the index of refraction for selected sizes. Size is determined by measuring the light intensity scattered by individual particles as they transit a laser beam of 0.780µm wavelength. Light scattered from particles into a cone from 30 to 60 degrees forward and 120 to 150 degrees backwards is reflected by a mangin mirror through a condensing lens to the detectors. A comparison of the signals from the open aperture detector and the masked aperture detector is used to accept only those particles passing through the center of the laser beam. The size of the particle is determined from the total scattered light. The index of refraction of particles can be estimated from the ratio of the forward to back scatter signals. A calibration diode laser is pulsed periodically during flight to ensure proper operation of the electronics. The shrouded inlet minimizes angle of attack effects and maintains isokinetic flow through the sensing volume so that volatilization of particles is eliminated.

OH is detected by direct laser induced fluorescence in the (0-1) band of the 2?-2? electronic transition. A pulsed dye-laser system produces frequency tunable laser light at 282 nm. An on-board frequency reference cell is used by a computer to lock the laser to the appropriate wavelength. Measurement of the signal is then made by tuning the laser on and off resonance with the OH transition.

Stratospheric air is channeled into the instrument using a double-ducted system that both maintains laminar flow through the detection region and slows the flow from free stream velocity (200 m/s) to 40 m/s. The laser light is beam-split and directed to two detection axes where it passes through the stratospheric air in multipass White cells.

Fluorescence from OH (centered at 309 nm) is detected orthogonal to both the flow and the laser propagation using a filtered PMT assembly. Optical stability is checked periodically by exchanging the 309 nm interference filter with a filter centered at 302 nm, where Raman scattering of N2 is observed.

HO2 is measured as OH after chemical titration with nitric oxide: HO2 + NO → OH + NO2. Variation of added NO density and flow velocity as well as the use of two detection axes aid in diagnosis of the kinetics of this titration. Measurements of ozone (by uv absorption) and water vapor (by photofragment fluorescence) are made as diagnostics of potential photochemical interference from the mechanism: O3 + hv (282 nm) → O(1D) + O2, followed by: O(1D) + H2O → OH + OH