Status
The measurement of gas phase peroxide species, H2O2 and CH3OOH, contribute to our scientific understanding of the photochemistry of trace gases and particles prior to and after their transport and processing through deep convective clouds. The PCIMS instrument used to make these measurements in the DC3/SEAC4RS mission is new and this will be its first use in an airborne science campaign.
The PCIMS instrument is a slightly modified CIMS instrument manufactured by THS Instruments LLC. Mechanically it consists of a differentially pumped quadrupole mass spectrometer. The instrument operates in negative ion mode and currently I- and O2- reagent ions are used to measure hydrogen peroxide and methylhydroperoxide, respectively, by the formation of cluster ions at masses 80 and 161. The reagent ions are produced by flowing a N2/CH3I/O2 mixture past a 210Po foil.
On the G-V, the PCIMS inlet system starts with a PFA Teflon lined heated G-V HIMIL inlet. From the HIMIL the inlet line is comprised of PFA Teflon and is also heated (Hot-Tube, Clayborn Lab). Analytical blanks are performed by diverting the ambient sample flow through a trap filled with Carulite 200 catalyst. Gas phase calibrations are performed through standard additions to ambient air. H2O2 is added from a urea hydrogen peroxide solid decomposition source or by the evaporation of a nano-fluidic flow of a dilute aqueous solution. CH3OOH is added by the evaporation of a nano-fluidic flow of a dilute aqueous solution. The ambient, calibration and reagent gases are vented overboard through the G-V common exhaust.
