85 1001 ;header lines file format index ATLAS, ELLIOT University of Miami MIXING RATIOS FROM WHOLE AIR SAMPLER CR-AVE 1 1 ;vol total vol 2006 01 22 2007 06 05 ;DATE RDATE 0 ;DX(1) Elapsed UT seconds from 0 hours on T/O DATE ;UTMID 46 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ;scale factors 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 UTSTART (sec) ;MMS data UTSTOP (sec) ;MMS data CCl3F (pptv) CFC 11 CCl2F2 (pptv) CFC 12 C2ClF5 (pptv) CFC 115 C2Cl2F4 (pptv) CFC 114 C2Cl3F3 (pptv) CFC 113 CHClF2 (pptv) HCFC 22 CH3CCl2F (pptv) HCFC 141b CH3CClF2 (pptv) HCFC 142b CHCl2F (pptv) HCFC 21 C2HCl2F3 (pptv) HCFC 123 C2HClF4 (pptv) HCFC 124 C2H2F4 (pptv) HFC 134a C2H4F2 (pptv) HFC 152a CBrF3 (pptv) Halon 1301 CBrClF2 (pptv) Halon 1211 C2Br2F4 (pptv) Halon 2402 OCS (pptv) Carbonyl sulfide CH3Cl (pptv) Methyl chloride C2H5Cl (pptv) Ethyl chloride CH3Br (pptv) Methyl bromide CH3I (pptv) Methyl iodide CHCl3 (pptv) Chloroform CH2Cl2(pptv) Methylene chloride C2H4Cl2 (pptv) 1,2Dichloroethane CH3CCl3 (pptv) Methyl chloroform CCl4 (pptv) Carbon tetrachloride C2Cl4 (pptv) Perchlorethylene CH3ONO2 (pptv) Methyl nitrate C2H5ONO2 (pptv) Ethyl nitrate C3H7ONO2 (pptv) Isopropyl nitrate C3H7ONO2 (pptv) n-propyl nitrate C4H9ONO2 (pptv) 2-butyl nitrate CH2Br2 (pptv) Methylene bromide CHBr2Cl (pptv) Dibromochloromethane CHBr3 (pptv) Bromoform C2H6 (pptv) Ethane C2H2 (pptv) Ethyne C3H8 (pptv) Propane C4H10 (pptv) i-Butane C4H10 (pptv) n-Butane C6H6 (pptv) Benzene CH4 (ppbv) Methane N2O (ppbv) Nitrous Oxide CO (ppbv) Carbon monoxide 0 ;number of special comment lines (specific to this flight) 22 ;number of normal comment lines (occur each flight) UTSTART IS THE TIME THE CANISTER BEGAN FILLING UTMID IS THE AVERAGE OF THE START AND STOP TIMES UTSTOP IS THE TIME THE CANISTER FINISHED FILLING 0.0 - Concentration Below Detection Limit Negative mixing ratios for benzene are reported in cases when a small, constant blank value is subtracted from all the sample values. In previous missions, CO measurements from WAS appeared high in the lower stratosphere (O3>125 ppb) by 10-25 ppb due to canister artifacts. CRAVE data appear less affected by this artifact and are reported with no correction. Some trace gas data were deleted from the archive due to contamination associated with new canisters first used during the mission, and outliers associated with these canisters have been removed from the data set. Mixing ratios of CFCs 114 and 115 are undergoing recalibration, but data reported here is on the same scale as all prior NASA missions. Expected corrections will be approximately 1.25 for CFC115 and 1.15 for CFC114. Additional bromocarbon species were measured for a subset of the samples during CRAVE and are available on request from the PI. For questions, contact Elliot Atlas, RSMAS, University of Miami, Ph: 305-421-4128, e-mail: eatlas@rsmas.miami.edu UTMID UTSTART UTSTOP CFC_11 CFC_12 CFC_115 CFC_114 CFC_113 HCFC_22 HCFC_141b HCFC_142b HCFC_21 HCFC_123 HCFC_124 HFC_134a HFC_152a Halon_1301 Halon_1211 Halon_2402 OCS CH3Cl EtCl CH3Br CH3I CHCl3 CH2Cl2 1_2_dichloroethane CH3CCl3 CCl4 C2Cl4 MeONO2 EthONO2 i_PropONO2 n_PropONO2 2_ButylONO2 CH2Br2 CHClBr2 CHBr3 Ethane Ethyne Propane Isobutane n_Butane Benzene CH4_ppbv N2O_ppbv CO_ppbv 65961 65950 65971 251 533 6.5 14.2 78.6 171 17.8 16.3 0.2 0.21 0.84 37.7 3.4 2.11 4.16 0.45 438 577 0.35 8.08 0 6.53 14.2 1.81 14.2 93 0.53 2.81 0.27 0.13 0 0 0.55 0.04 0.09 478 82 39 1.6 3.6 0.7 1758 318.7 78 66374 66359 66389 251 535 6.73 14.3 79.1 169 17.6 16.4 0.19 0.18 0.88 36.6 3.8 2.58 4.1 0.44 474 567 0.24 8.05 0 5.96 12 1.32 13.8 94 0.37 2.23 0.16 0 0 0 0.54 0 0.07 389 53 19 0.9 3.1 0.2 1754 319 65 66800 66778 66821 251 535 6.95 14.2 79.4 169 17.3 16 0.18 0.17 0.84 36.8 3.2 2.54 4.13 0.46 403 549 0.25 7.76 0 5.47 11.9 0.92 12.9 94 0.21 1.59 0 0 0 0 0.4 0 0 340 33 13 0.7 1.8 0 1754 318.5 54 67236 67208 67263 253 540 6.75 14.6 80.3 171 17.6 16.4 0.19 0.18 0.85 36.2 3.4 2.5 4.08 0.42 475 550 0.26 7.85 0 5.07 11.7 0.86 12.3 93 0.18 1.04 0 0 0 0 0.35 0 0 297 24 8 0.5 2.4 0.2 1748 317.8 43 67675 67652 67697 254 545 6.85 14.6 84.6 168 99999 16.1 0.19 0.15 0.8 36.2 4 2.7 4.11 0.44 99999 544 0.12 99999 0 99999 99999 99999 99999 99999 0.06 99999 99999 99999 99999 99999 99999 99999 99999 331 99999 10 0.3 0.5 0.1 1752 319.2 54 67728 67706 67750 254 540 6.7 14.4 80.1 167 17.7 16.9 0.21 0.17 0.78 36 3.6 3.02 4.22 0.43 470 564 0.19 7.79 0 5.64 12.1 1.12 12.9 94 0.26 2.11 0.06 0 0 0 0.46 0 0 333 34 14 0.6 1.1 -0.3 1750 318.9 51 68162 68138 68186 255 536 6.65 14.5 80.2 167 17.7 16.8 0.25 0.15 0.79 35.7 3.6 2.82 4.09 0.43 488 559 0.27 8.04 0 5.95 12.3 1.39 12.8 95 0.25 2.05 0.13 0 0 0 0.55 0.03 0 333 33 12 0.5 1.5 -0.1 1749 318.8 51 68601 68574 68628 249 535 6.32 14.2 79.3 167 17.3 16.2 0.22 0.18 0.89 34.6 3.2 2.57 4.03 0.44 474 554 0.21 7.77 0 5.03 11.2 0.79 12.1 93 0.18 1.4 0 0 0 0 0.37 0 0 325 33 13 0.7 1.3 -0.5 1753 318.5 54 69042 69017 69066 251 538 6.58 14.4 79.9 166 17.5 16.6 0.18 0.08 0.86 35.2 3.5 2.84 4.1 0.43 434 556 0.24 7.89 0 5.68 11.7 1.32 12.8 94 0.29 2.6 0.15 0 0 0 0.54 0 0.05 328 33 14 0.5 1.6 0 1752 319.1 55 69480 69454 69506 245 536 6.52 14 79.8 169 17.3 16.4 0.19 0.15 0.86 36.5 4.1 2.36 4.01 0.47 99999 99999 99999 99999 99999 6.08 12.4 1.95 13.4 96 0.33 99999 99999 99999 99999 99999 0.65 0.04 0.05 99999 42 99999 99999 99999 2.2 1748 319.5 99999 69925 69894 69955 249 534 6.77 14.2 78.9 163 17 16.6 0.18 0.13 0.78 35 3.3 2.84 4.08 0.48 410 554 0.24 7.66 0.07 4.9 11 0.79 12 93 0.17 1.62 0 0 0 0 0.37 0 0 314 31 11 0.6 1.8 -0.1 1750 318.4 54 70368 70343 70392 250 535 6.77 14.3 83.7 166 17.9 16.3 0.21 0.16 0.82 36.1 3.3 2.45 4.06 0.52 458 547 0.27 7.75 0 6.55 12 3.31 19.2 103 0.93 3.79 0.88 0.51 0 0 0.92 0.14 0.59 319 41 17 1.2 4.4 1.1 1746 319 55 70805 70780 70830 250 530 6.56 14.3 80 165 17.6 16.2 0.21 0.15 0.71 35.8 2.9 2.45 4.1 0.47 476 543 0.2 7.66 0 6.28 12.2 2.01 15.1 96 0.5 3.15 0.39 0.15 0 0 0.69 0.06 0.14 316 37 15 0.8 2.4 0.4 1744 319 53 71250 71218 71282 252 536 6.82 14.4 79.3 168 17.4 16.9 0.2 0.14 0.75 35.6 3.4 2.72 4.15 0.41 463 565 0.18 8.1 0 5.66 11.3 1.1 13.1 94 0.22 2 0.17 0 0 0 0.48 0 0 339 40 14 0.5 1.6 -0.2 1750 319 55 71697 71670 71724 251 535 6.62 14.3 84.8 168 17.4 15.8 0.18 0.17 0.73 35.9 3 2.34 4.08 0.48 99999 539 0.23 99999 0 99999 10.5 99999 99999 99999 0.25 1.37 99999 99999 99999 99999 99999 99999 99999 320 37 15 0.6 2.4 0.3 1750 319.7 57 71760 71733 71786 253 537 6.94 14.4 80.3 167 17.4 16.2 0.19 0 0.81 35.9 3.4 2.39 4.18 0.43 471 550 0.24 7.84 0 6 11.9 1.61 14.6 96 0.38 3.19 0.26 0 0 0 0.66 0 0 318 37 15 0.6 5.3 0.1 1746 318.5 56 71924 71901 71947 254 539 6.91 14.3 79.5 170 17.4 16.2 0.21 0.09 0.82 35.1 3.6 2.28 4.21 0.43 502 543 0.21 7.85 0 6.61 12.4 2.29 15 95 0.52 3.48 0.45 0 0 0 0.8 0.07 0.17 336 40 19 1 2.4 0.7 1748 319.2 58 72092 72075 72108 254 542 7.19 14.5 79.5 171 17.7 16.6 0.22 0.15 0.77 36.7 3.8 2.57 4.22 0.44 494 558 0.25 7.95 0 7.19 15.1 3 15 95 0.79 3.61 0.52 0.15 0 0 0.81 0.07 0.11 433 61 40 1.9 8.3 2.6 1756 319.5 70 72251 72236 72266 252 538 6.65 14.4 78.9 171 17.8 16.3 0.18 0.2 0.8 36.9 4.2 2.41 4.22 0.47 463 548 0.22 7.91 0.03 7.12 14.5 2.71 14.6 95 0.75 6.26 0.56 0.12 0 0 0.84 0.05 0.1 370 46 24 1.6 5.1 0.7 1750 319.5 56 72405 72393 72417 247 548 6.91 14.3 80.1 173 18 17.1 0.22 0.17 0.87 38.5 3.7 2.88 4.16 0.45 99999 99999 99999 99999 0.09 7.96 17 3.72 15.1 95 0.93 5.43 1.64 99999 99999 0.54 0.93 0.1 0.43 443 62 69 2.6 5.8 2.1 1758 319.8 99999 72555 72545 72564 253 544 7.25 14.7 80.8 168 17.6 16.7 0.2 0.13 0.82 37.2 3.3 3.14 4.2 0.46 496 547 0.2 7.74 0.05 6.57 11.8 2.24 15.7 96 0.77 5.36 0.83 0.28 0 0 0.9 0.12 0.64 275 24 12 0.8 2.2 1.3 1733 319.3 53 72701 72692 72709 255 541 6.87 14.6 80.5 165 18.1 17.1 0.2 0.09 0.84 38 3.5 2.96 4.23 0.47 481 544 0.25 7.77 0 6.81 13.8 2.82 16 95 0.89 6.05 0.96 0.33 0 0 0.97 0.12 0.54 326 39 20 1.2 3.3 2.2 1743 319.6 55 72844 72836 72852 253 540 6.67 14.5 80.5 174 18.7 17.3 0.23 0.17 0.86 38.7 3.9 2.73 4.33 0.44 498 578 0.42 8.16 0.06 9.25 22.7 6.79 16.1 96 1.62 3.64 0.87 0.79 0 0 0.99 0.12 0.4 593 112 70 4.3 7.9 9.1 1772 319.8 88 73255 73241 73269 256 542 6.88 14.5 80.1 170 18.2 16.8 0.21 0.11 0.79 37.4 4 2.74 4.26 0.49 514 550 0.26 7.83 0 6.94 14.7 2.65 15.1 95 0.79 5.91 0.71 0.15 0 0 0.83 0.07 0.23 372 44 26 1.7 4.5 1.8 1749 319.5 66 73676 73657 73694 250 538 6.93 14.3 76.9 164 99999 16.5 0.21 0.13 0.8 37.3 3.8 2.58 4.17 99999 99999 99999 0.07 99999 0 99999 11.6 99999 99999 99999 0.13 99999 99999 99999 99999 99999 99999 99999 99999 404 49 27 1 2.3 0.4 1762 320.2 62 73722 73703 73741 251 540 7.07 14.4 80 168 17.8 16.4 0.19 0.15 0.9 36.6 3.5 2.91 4.17 0.46 463 556 0.25 7.94 0 5.87 12.2 1.44 14.3 95 0.44 2.78 0.21 0 0 0.27 0.56 0 0.06 339 41 17 1.2 4.3 0.1 1745 318.7 50 74162 74130 74194 252 541 6.56 14.5 78.7 168 17.5 17.1 0.22 0.13 0.81 36.4 3.8 2.53 4.28 0.47 476 555 0.24 7.77 0 4.9 11.4 0.55 12.5 93 0.13 1.31 0 0 0 0 0.28 0 0 303 25 9 0.5 2.2 0.3 1750 318.2 46 74434 74403 74465 245 536 6.66 14.3 77.5 167 17.5 16.6 0.15 0.15 0.77 34.5 3.6 2.8 4.06 0.42 477 540 0.18 7.71 0.04 4.64 13.7 0.4 12.3 90 0.14 0.87 0 0 0 0.37 0.22 0 0 299 27 8 1.3 3.9 0.4 1750 318.3 47 74619 74592 74646 252 534 6.61 14.5 77.5 167 17.3 16.4 0.2 0.1 0.84 35.4 3.6 2.99 4.14 0.43 476 549 0.19 7.69 0 4.76 10.8 0.42 12.5 92 0.13 1.19 0 0 0 0 0.24 0 0 321 32 11 0.7 2.9 -0.1 1749 318.7 46 74795 74774 74816 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 74959 74943 74974 253 536 6.65 14.6 79.4 172 18.1 16.2 0.21 0.12 0.79 36.8 3.7 2.68 4.19 0.43 505 555 0.39 8 0 7.5 16.4 2.87 14.9 95 0.74 3.1 0.36 0 0 0 0.77 0.06 0 435 64 37 1.8 5.7 1.8 1760 319.8 65 75116 75102 75130 253 532 6.74 14.5 79.3 172 18.4 16.9 0.23 0.11 0.78 36 3.6 2.87 4.19 0.45 511 557 0.33 7.89 0 8.03 17.5 3.48 15 96 0.93 2.92 0.46 0.22 0 0 0.79 0.07 0.11 483 76 48 2.8 6.3 2.3 1760 319.8 66 75538 75519 75557 253 536 6.88 14.4 80.3 174 17.9 16.7 0.2 0.14 0.79 35.2 3.1 2.67 4.21 0.46 487 559 0.25 8.04 0 6.6 13.7 1.87 14.4 96 0.58 2.5 0.24 0 0 0 0.63 0.05 0.12 408 53 28 1.2 4.6 0.5 1756 319.4 64 75981 75944 76017 248 533 7.06 14.5 79.1 167 17.4 16.5 0.21 0.11 0.92 35.5 3.1 2.66 4.02 0.47 463 547 0.18 7.73 0 4.87 11.4 0.77 12.8 92 0.18 1.27 0.14 0 0 0 0.35 0 0 271 25 8 0.6 2 0 1744 316.8 40 76447 76405 76488 245 530 6.99 14.4 80.7 167 99999 16.2 0.2 0.11 0.89 34.7 3.1 2.68 3.93 99999 99999 511 0.13 99999 0 99999 99999 99999 99999 99999 0 99999 99999 99999 99999 99999 99999 99999 99999 220 25 99999 0.5 2.6 1.8 1741 316.2 38 76540 76497 76582 246 532 7.08 14.6 78.1 171 17.1 16.3 0.22 0.15 0.85 35.5 3.5 2.27 3.87 0.44 465 532 0.19 7.41 0 3.91 9.8 0.29 12.7 89 0.07 0.55 0 0 0 0 0.18 0 0 209 17 4 0.4 2.2 -0.4 1743 315.5 34 77020 76970 77070 241 527 6.78 14.5 78 172 17 16.1 0.19 0.14 0.79 35.2 3.6 2.35 3.77 0.39 459 522 0.21 7.15 0 3.75 9.8 0.35 12 88 0.06 0.44 0 0 0 0 0.16 0 0 135 14 3 0.4 2.9 -0.1 1733 312.7 37 77509 77459 77558 238 524 7.25 14.2 77 166 16.8 15.9 0.21 0.15 0.76 34 3.4 2.45 3.75 0.42 449 519 0.19 7.17 0 3.46 9.4 0.29 11.5 87 0 0.35 0 0 0 0 0.17 0 0 137 12 4 0.6 2.2 -0.4 1730 312 33 77996 77946 78046 237 524 7.45 14.4 77.2 165 16.7 15.6 0.2 0.13 0.79 34.5 3.4 2.52 3.68 0.4 460 516 0.16 7.15 0 3.3 9 0.22 11.7 88 0 0.41 0 0 0 0 0.11 0 0 126 10 3 0.5 2 -0.3 1722 310.2 32 78485 78434 78535 220 515 6.99 14 73.7 163 16.2 15.9 0.21 0.14 0.76 99999 99999 2.41 3.47 0.39 99999 535 99999 99999 99999 3.49 10.1 0.62 11.6 99999 0.18 0.79 99999 99999 99999 99999 0.14 0 0 109 99999 99999 99999 99999 99999 99999 99999 99999 78966 78922 79009 239 521 6.98 14.4 76.1 165 16.7 15.9 0.18 0.1 0.81 34.5 3.3 2.2 3.72 0.41 398 518 0.19 7.28 0 3.27 9.3 0.25 11.6 86 0.06 0.37 0 0 0 0 0.14 0 0 152 14 6 0.4 2 -0.2 1731 312.4 28 79130 79095 79165 240 518 6.54 14 75.9 164 16.8 16 0.19 0.14 0.78 34.6 3.7 2.51 3.81 0.42 459 520 0.18 7.36 0 3.99 10.3 0.42 12.2 87 0.07 0.52 0 0 0 0 0.2 0 0 216 23 99999 0.5 1.6 1 1733 313.5 29 79350 79322 79377 248 533 6.39 14.5 77.9 171 17.4 16.1 0.19 0.11 0.73 35.4 3.3 2.32 4.11 0.44 467 555 0.2 7.75 0 5.32 11.9 0.89 12.9 92 0.18 0.98 0 0 0 0 0.39 0 0 322 30 19 0.6 1.8 -0.3 1752 318.6 44 79555 79535 79574 250 535 6.91 14.3 79.4 169 17.7 16.4 0.19 0.16 0.79 35.8 3.4 2.63 4.2 0.46 487 562 0.26 7.87 0 5.54 11.8 1.43 13.9 95 0.34 1.93 0 0 0 0 0.57 0 0 363 45 17 0.8 3.4 0.6 1757 319 53 79746 79732 79760 253 534 6.61 14.3 79.8 169 99999 16.2 0.21 0.11 0.83 36 3.6 2.14 4.03 99999 99999 545 0.14 99999 0 3.73 12.1 99999 99999 99999 0.31 99999 99999 99999 99999 99999 99999 99999 99999 449 99999 34 1.1 2.6 0.5 1763 320.2 62 79782 79769 79795 252 536 6.98 14.3 79.8 169 18.1 16.4 0.18 0.14 0.9 37.1 3.8 2.4 4.24 0.46 466 581 0.28 8.23 0 6.57 13.9 2.59 15.5 96 0.76 2.48 0.4 0 0 0 0.69 0.09 0 495 90 36 1.2 4.1 1.3 1763 319.6 78 79962 79952 79971 252 536 6.87 14.4 81.3 170 18.2 16.7 0.21 0.15 0.88 36.8 3.9 2.62 4.3 0.5 481 579 0.25 8.35 0 7.52 15 3.4 16.6 98 1.08 3.1 0.85 0.78 0 0 0.93 0.12 0.6 530 92 49 2.3 6 4.6 1767 319.6 76 80138 80129 80146 252 538 6.99 14.4 80.6 171 18.5 16.5 0.22 0.15 0.88 37.9 3.9 2.63 4.28 0.48 495 558 0.27 8.18 0.07 7.85 16.3 3.66 16.3 97 1.27 5.18 1.24 0.86 0.28 0 1.02 0.1 0.58 515 73 47 2.9 5.5 5.4 1767 319.7 71 80310 80303 80317 251 540 6.9 14.6 79.4 173 18.3 16.5 0.23 0.16 0.8 38 3.8 2.54 4.2 0.44 421 570 0.28 8.2 0.15 8.07 16.2 4.05 16.3 96 1.34 5.72 1.44 1.02 0.35 0.48 1.05 0.12 0.84 502 72 39 2.2 5.4 7.4 1758 319.7 76 80481 80474 80487 244 540 7.02 14.2 79.1 172 18 16.5 0.2 0.11 0.87 37.8 4 2.76 4.29 0.48 99999 99999 99999 99999 0.17 7.84 17.2 4.47 16.4 95 1.25 99999 99999 99999 99999 99999 1.03 0.11 0.76 491 73 45 3.5 8.6 7.5 1764 319.6 99999